the reactive chemisorption of carbon dioxide at mg(100) surface

x-ray photoelectron and electron energy loss spectroscopic (xps-eels) studies reveal that the following species are present when a mixture of co2 and water vapour is exposed to the clean mg(100) surface at 110k: co3(a), c(a) ch(a), oh(a). the reactive chemisorptions of co2 and h2o vapour coadsorbed on a mg surface leads to the formation of ch bond. increasing the temperature to 400 k shows the peaks in the c(1s) region of the spectrum disappears suggesting the ch containing species are not stable at 400k.